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Multiple Choice Unique Answer

Que 1:) Toluene is nitrated and the resulting product is reduced with tin and hydrochloric acid. The product so obtained is diazotised and then heated with cuprous bromide. The reaction mixture so formed contains

mixture of o- and p-bromotoluenes
mixture of o- and p-dibromobenzenes
mixture of o- and p-bromoanilines
mixture of o- and m-bromotoluenes

Que 2:) Phenol, when it first reacts with concentrated sulphuric acid and then with concentrated nitric acid, gives

2,4,6-trinitrobenzene
o-nitrophenol
p-nitrophenol
nitrobenzene

Que 3:) Which of the following factors is of no significance for roasting sulphide ores to the oxides and not subjecting the sulphide ores to carbon reduction directly?

Metal sulphides are thermodynamically more stable than CS2
CO2 is thermodynamically more stable than CS2
Metal sulphides are less stable than the corresponding oxides
CO2 is more volatile than CS2

Que 4:) α-D-(+)-glucose and β-D-(+)-glucose are

conformers
epimers
anomers
enantiomers

Que 5:) Among the following substituted silanes the one which will give rise to cross linked silicone polymer on hydrolysis is

R4Si
RSiCl3
R2SiCl2
R3SiCl

Que 6:) In a compound atoms of element Y from ccp lattice and those of element X occupy 2/3rd of tetrahedral voids. The formula of the compound will be

X4Y3
X2Y3
X2Y
X3Y4

Que 7:) Amount of oxalic acid present in a solution can be determined by its titration with KMnO4 solution in the presence of H2SO4. The titration gives unsatisfactory result when carried out in the presence of HCl, because HCl

gets oxidised by oxalic acid to chlorine
furnishes H+ ions in addition to those from oxalic acid
reduces permanganate to Mn2+
oxidises oxalic acid to carbon dioxide and water

Que 8:) Which one of the following pairs of species have the same bond order?

CN- and NO+
CN- and CN+
O- and CN-
NO+ and CN+






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